Publishchemidea, 2014 No: 9
Submitted: Tuesday, February 25th, 2014
| Title of the idea: |
Radical reaction of benzylic ROMgX with alpha,beta unsaturated olefines |
| Author of the idea: |
Ramesha |
| Email of the author |
ramesha63@hotmail.com |
| Key words for search: |
Grignard, AIBN, Cyanide, nitro |
| Explain briefly the idea |
The benzyllic intermediate ROMgX during Grignard reaction can be radically trapped with alpha,beta-unsaturated cyanides/ketones/nitrocompounds.
One can also try basic condition. There might be a possibility of O/C reaction
|
| Why do you think this idea will work? |
In making interesting compounds having gamma hydroxyl substrates. |
| Do you have any experimental proof? |
No |
| Literature reference |
No |
| Where it is useful? |
Academic |
| Do you plan to work on this idea in near future? |
Yes |
| Interested in collaboration? |
Yes |
| Nature of idea: |
Theoretical/experimental |
| Youtube link: |
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