Publishchemidea, 2015 No: 16
Submitted: Wednesday, July 1st, 2015
| Title of the idea: |
Kinetic resolution of aldehydes |
| Author of the idea: |
Ramesha |
| Email of the author |
ramesha63@hotmail.com |
| Key words for search: |
CBS, L-diphenyl prolinol, kinetic resolution, aldehyde |
| Explain briefly the idea |
Aldehyde can be easily protected as acetal. This concept is used for preparing L-Diphenyl prolinol and an aldehyde acetal. If 0.5 eq of L-diphenyl prolinol is used, probably one of the aldehyde isomer can for acetal easily. other isomer can stay back in the solution. This can be easily separated by either column purification or by hydrazine formation/by any other physical techniques.
|
| Why do you think this idea will work? |
In organic synthesis |
| Do you have any experimental proof? |
No. If some one is interested, you can contact me at ramesha63@hotmail.com . I can suggest best possible condition. |
| Literature reference |
None |
| Where it is useful? |
Academic |
| Do you plan to work on this idea in near future? |
NO |
| Interested in collaboration? |
Yes |
| Nature of idea: |
Theoretical/experimental |
| Youtube link: |
|
Download article as PDF
